Matrices : Concepts of m x n (m≤3, n≤3) real matrices, operations of addition, scalar multiplication and multiplication of matrices. Transpose of a matrix. Determinant of a square matrix. Properties of determinants (statement only). Minor, cofactor and adjoint of a matrix. Nonsingular matrix. Inverse of a matrix. Finding area of a triangle. Solutions of system of linear equations. (Not more than 3 variables).
Aromatic Aldehydes – Preparation by Gattermann, Gattermann – Koch, Rosenmund and Stephen’s method. Reactions – Perkin, Benzoin and Cannizzaro.
Haloarenes – Nucleophilic substitution, cine substitution (excluding mechanism).
Phenols – halogenation, sulfonation, nitration, Reimer-Tiemann and Kolbe reactions.
Aromatic Compounds
Carboxylic Acids – Hydrolysis of esters (mechanism excluded) and cyanides; Hunsdicker and HVZ reactions.
Aldehydes and Ketones – Preparation from esters, acid chlorides, gem-dihalides, Ca-salt of carboxylic acids.
