Gaseous state
Measurable properties of gases. Boyle’s Law and Charles Law, absolute scale of temperature, kinetic theory of gases, ideal gas equation – average, root mean square and most probable velocities and their relationship with temperature.
Dalton’s Law of partial pressure, Graham’s Law of gaseous diffusion. Deviations from ideal behavior. Liquefaction of gases, real gases, van der Waal’s equation; Numerical problems.
Aromatic Aldehydes – Preparation by Gattermann, Gattermann – Koch, Rosenmund and Stephen’s method. Reactions – Perkin, Benzoin and Cannizzaro.
Haloarenes – Nucleophilic substitution, cine substitution (excluding mechanism).
Phenols – halogenation, sulfonation, nitration, Reimer-Tiemann and Kolbe reactions.
Aromatic Compounds
Carboxylic Acids – Hydrolysis of esters (mechanism excluded) and cyanides; Hunsdicker and HVZ reactions.
Aldehydes and Ketones – Preparation from esters, acid chlorides, gem-dihalides, Ca-salt of carboxylic acids.
