Aromatic Compounds
Benzene – Kekule structure, aromaticity and Hückel rule. Electrophilic substitution – halogenation, sulfonation, nitration, Friedel Crafts reaction, ozonolysis. Directive influence of substituents in monosubstituted benzenes. Amines – Preparation from reduction of nitro compounds; Formation of diazonium salts and their stability; Replacement of diazonium group with H, OH, X (halogen), CN and NO2, diazocoupling and reduction.
Chemical Bonding and Molecular Structure
Valence electrons, the Octet rule, electrovalent, covalent and coordinate covalent bonds with examples; Properties of electrovalent and covalent compounds. Limitations of Octet rule (examples); Fajan’s Rule.
Directionality of covalent bonds, shapes of poly-atomic molecules (examples); Concept of hybridization of atomic orbitals (qualitative pictorial approach) : sp, sp2, sp3 and dsp2.
The Periodic Table and Chemical Families
Radioactivity and Nuclear Chemistry
Atomic Structure
Atoms, Molecules and Chemical Arithmetic :
